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Removal Process of Negatively Charged Impurities using Metal-Cellulose Fiber Composite
Using a stable, predominantly positively charged, composite structure to separate negatively charged impurities from water

 

Please note, header image is purely illustrative. Source: unsplash.com/photos/Y10FXNqFdvk, Unsplash Licence

Background

The process of removing negatively charged impurities such as fluoride, nitrate, nitrite, phosphate, sulfate, and other ions from water is necessary in order to effectively make cleaner water. There have been multiple processes and methods implemented to achieve this, however, there hasn’t been an appropriate balance between cost and efficiency. The most efficient processes are often the most costly and require materials that aren’t readily available, whereas the cheapest methods are the least efficient.There is also the issue regarding environmental damage through toxic byproducts and contamination from certain methods of water purification.Therefore a need exists for a process that can separate negatively charged impurities from water and is cost‑effective.

Technology

This technology revolves around using a composite containing positively charged metal ions and a carboxylated cellulose fibrous scaffold. The carboxylated cellulose fibrous scaffold includes macro and nanoscale fibers and they have a chemical structure that includes anhydroglucose units. The primary and secondary hydroxyl groups are modified to negatively charged groups (such as carboxylate groups) via nitro‑oxidation, TEMPO oxidation, per‑iodate oxidation, perchlorite oxidation, carboxymethylation, and etc.During this step, through the use of mechanical treatment (homogenization, microfluidization, ball milling, cryo‑crushing, steam explosions, and etc.) or combined chemical and mechanical treatments, the cellulose microfibers can be converted into nanofibers. Then, the negatively charged cellulose fibers are treated with solutions of metal ions that have high positive charges at room temperature. A stable composite structure is formed through the interactions between the oxygen atoms of the hydroxyl/carboxylate groups on the cellulose chains and the positively charged metal ions. This composite structure is predominantly covered with the positive metal ions and can be used to effectively remove any negatively charged impurities from water.Finally, if need be, the composite can be easily separated from the negatively charged impurities after remediation without the risk of secondary contaminations.

Advantages

A cost‑effective and sustainable process.More efficient than conventional processes.Zero toxicity in this method.Expeditious process, it is done within 5 minutes.No secondary contamination.The composite can be recycled. 

Application

This technology is used to separate negatively charged impurities from water.

Inventors

Benjamin Hsiao, Distinguished Professor, Chemistry
Sunil Sharma, Research Scientist, Chemistry
Priyanka Sharma, Research Scientist, Chemistry
Ken Johnson, Ph.D. Student, Chemistry

Licensing Potential

Development partnerCommercial partnerLicensing 

Licensing Status

Available for licensing.

Licensing Contact

Donna Tumminello, Assistant Director, Office of Technology Licensing, donna.tumminello@stonybrook.edu, 6316324163

Patent Status

Provisional patent

PCT/US19/58703

Tech Id

050-9037